Managed by World Cup and seven-time Bundesliga winner Klaus Augenthaler, Bayern will count legendary figures such as Lothar Matthaus, Bixente Lizarazu, Roy Makaay and Ze Roberto among their number.
Meanwhile, fresh from retiring last summer, former Spain midfielder Xabi Alonso will represent each of his former clubs for 45 minutes apiece in this weekend's fixture.
Money raised from the charity game will help to fund a variety of projects for the LFC Foundation and charity partners. You can watch the match for free, live on the official LFC Facebook page, LFCTV GO, Sky channel 429 and Virgin Media channel 544 (3pm GMT kick-off).
Confirmed Bayern Munich Legends squad and shirt numbers
1 - Hans-Jorg Butt
2 - Matthias Zimmermann
3 - Bixente Lizarazu
3 - Michael Tarnat
5 - Daniel van Buyten
6 - Martin Demichelis
7 - Roy Makaay
8 - Hans Pflugler
9 - Giovane Elber
10 - Lothar Matthaus
11 - Marcel Witezcek
12 - Uwe Gospodarek
13 - Paulo Sergio
14 - Xabi Alonso
15 - Ze Roberto
16 - Andreas Ottl
20 - Luca Toni
21 - Alexander Zickler
34 - Michael Sternkopf
35 - Zvjezdan Misimovic