The Reds’ fourth-place finish in the Premier League last season earned them automatic qualification for the 2018-19 edition of the tournament in which they were runners-up in May.
The play-offs for the competition concluded on Wednesday evening and thereby finalised the pot placings of the 32 teams set to contest the group stage from mid-September onwards.
The draw takes place in Monaco from 5pm BST on Thursday. Stay logged on to Liverpoolfc.com for full details, including confirmed fixture dates.
Liverpool, who cannot meet a fellow English club at this stage, will be grouped with one team from each of the following pots.
Pot one
Real Madrid
Atletico Madrid
Barcelona
Bayern Munich
Juventus
Paris Saint-Germain
Lokomotiv Moscow
Pot two
Borussia Dortmund
FC Porto
Shakhtar Donetsk
Benfica
Napoli
AS Roma
Pot four
Viktoria Plzen
Club Brugge
Galatasaray
Young Boys
Inter Milan
Hoffenheim
Crvena zvezda
AEK Athens