The full-back is named in defence in place of James Milner, who is ruled out due to a hamstring injury, while Georginio Wijnaldum and Xherdan Shaqiri start in midfield.
Naby Keita and Fabinho are on the bench.
Liverpool: Alisson, Alexander-Arnold, Lovren, Van Dijk, Robertson, Henderson, Wijnaldum, Shaqiri, Mane, Salah, Firmino.
Subs: Mignolet, Clyne, Fabinho, Keita, Sturridge, Lallana, Origi.