The defender has recovered from a slight knock to take his place in the Reds’ line-up at the Stadio San Paolo.
In total, Jürgen Klopp makes three changes to the team deployed against Newcastle United on Saturday, with Roberto Firmino, Jordan Henderson and James Milner coming in for Divock Origi, Alex Oxlade-Chamberlain and Georginio Wijnaldum.
Liverpool: Adrian, Alexander-Arnold, Matip, Van Dijk, Robertson, Fabinho, Milner, Henderson, Mane, Salah, Firmino.
Subs: Kelleher, Wijnaldum, Lovren, Gomez, Oxlade-Chamberlain, Lallana, Shaqiri.