The defender is named alongside Virgil van Dijk after recovering from an injury that kept him out of last weekend’s victory at Chelsea.
Thiago Alcantara is ruled out due to a minor fitness issue; however, fellow new signing Diogo Jota is named on the bench.
Liverpool: Alisson, Alexander-Arnold, Gomez, Van Dijk, Robertson, Fabinho, Wijnaldum, Keita, Mane, Salah, Firmino.
Subs: Adrian, Milner, Jones, Minamino, Jota, Origi, N. Williams.