The game, which is being played at Puskas Arena in Budapest, kicks off at 8pm GMT and will be broadcast live on BT Sport in the UK.
Goals, highlights, reaction and a full match replay will be available to watch on LFCTV GO shortly after full-time.
Make sure you don't miss any of the action this season by using the code 2021GOFREE to start a free one-month trial of LFCTV GO now – this can be cancelled at any time.
You can also follow live and interactive build-up, minute-by-minute updates and audio commentary, and reaction via our Match Centre on Liverpoolfc.com and the official LFC app from Tuesday morning.
For broadcast listings in your region, click here.