The full-back makes his first competitive appearance of the season after recovering from an ankle issue as the Reds make three changes.
Fabinho is named in midfield, while Roberto Firmino returns in attack, with the trio replacing Kostas Tsimikas, Naby Keita and Diogo Jota.
Liverpool: Alisson, Alexander-Arnold, Matip, Van Dijk, Robertson, Fabinho, Henderson, Elliott, Mane, Salah, Firmino.
Subs: Kelleher, Konate, Thiago, Keita, Gomez, Oxlade-Chamberlain, Minamino, Jota, Tsimikas.