The Reds, finalists in three of the previous five seasons, will be in pot two for Thursday’s draw in Istanbul, with the list of 32 qualified teams completed by this week’s play-offs.
Jürgen Klopp’s men will be placed in a group alongside one club from each of the other three pots, though cannot face a fellow Premier League side at this stage.
See Liverpool’s potential opponents by pot below…
Pot one
AC Milan, Ajax, Bayern Munich, Eintracht Frankfurt, Paris Saint-Germain, Porto, Real Madrid
Pot three
Bayer Leverkusen, Benfica, Borussia Dortmund, Internazionale, Napoli, Salzburg, Shakhtar Donetsk, Sporting CP
Pot four
Celtic, Club Brugge, Copenhagen, Dinamo Zagreb, Maccabi Haifa, Marseille, Rangers, Viktoria Plzen