After finishing second in Group A, the Reds will be unseeded in Monday’s draw for the competition’s first knockout round and face a group winner.
Jürgen Klopp’s men cannot be paired with Napoli or a fellow Premier League side and so the teams they can be drawn against are as follows.
- Bayern Munich
- Benfica
- Porto
- Real Madrid
The last-16 draw will be held from 11am GMT on Monday and ties are scheduled to take place across February and March 2023.