The full-back, who recently completed a transfer from Hull City, will figure in Red for the first time at Berlin’s Olympiastadion.
Klopp also revealed he plans to utilise the opportunity to give as many players as possible some game time in the encounter in Germany’s capital city.
LFCTV GO: Our exclusive chat with the boss in Germany
Asked whether Robertson would make his bow for the club, the manager told Liverpoolfc.com in Bavaria: “Yes. Tomorrow is a game where we will use all the opportunities we have to change because we have four games in one week from tomorrow onwards, so we have to deal with it.
“Tomorrow we will give all the players we take with us the opportunity to play – and that includes Andrew also.
“A few boys will stay here and do a bit of recovery work, or what they need to do – maybe some running! Then we have games on Tuesday and Wednesday, then Saturday again. We will deal with the intensity, but tomorrow all of the boys we take with us will play.”
Saturday's friendly clash with Hertha BSC will be shown live on LFCTV and LFCTV GO.