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The duo missed last night’s 3-0 win over Bayern Munich due to injury, but both are back in the XI for the clash with the La Liga side.
Elsewhere, Danny Ward starts in goal, while Sadio Mane retains his place in the team.
Philippe Coutinho, Mohamed Salah, Dejan Lovren and Alberto Moreno are rested for the fixture and are not in the matchday squad.
Liverpool: Ward, Flanagan, Gomez, Klavan, Milner, Can, Wijnaldum, Lallana, Woodburn, Mane, Solanke.
Subs: Karius, Mignolet, Firmino, Henderson, Grujic, Robertson, Matip, Kent, Ejaria, Alexander-Arnold, Origi.