The game is scheduled to be played on Sunday January 26.
Barclays FA Women’s Super League and FA Women’s Championship clubs enter the competition at this stage, resulting in 16 ties being drawn.
Last season, the Reds reached the quarter-finals of the competition before losing out to Manchester City.
Liverpool Women were No.15 in the bag and will play a side they faced in the Continental Cup back in November, with the Reds emerging 6-0 winners on that occasion.